Dr Patrick Cullen

Patrick Cullen
MChem, PhD, FHEA

Senior Lecturer in Renewable Energy
Admissions Lead for Chemical Engineering, Admissions Lead for Sustainable Energy Engineering, EDI Co-Lead - Culture and Policy

School of Engineering and Materials Science
Queen Mary University of London
ORCID Google Scholar LinkedIn

Research

Energy materials, Batteries, Catalysis, Operando studies, Neutron scattering

Interests

My expertise is in synthesising scalably made nanomaterials and embedding them into energy devices for increased performance. These include devices such as Li-ion batteries, Na-ion batteries and hydrogen fuel cells. I also develop novel operando techniques for probe the materials in energy devices as they work. My work takes place in the lab at Queen Mary or at neutron or synchrotron X-ray sources such as ISIS and Diamond.


Interests

Our mission is to pioneer the development of new materials and integrate them into innovative applications and devices. We focus on addressing critical challenges in energy storage, environmental sustainability, and advanced manufacturing.

Our vision is to be a leading hub for groundbreaking materials research and to drive the transition to a more sustainable and technologically advanced future.

Research Themes and Areas of Interest

Core Research Areas: Our lab specializes in the interdisciplinary fields of material science, chemistry, and physics, with a primary focus on designing novel materials and leveraging them for practical applications.

Current Projects

*Operando Neutron Scattering of Electrochemical Devices: Utilizing advanced neutron scattering techniques to understand the in-situ behavior of electrochemical devices, enhancing their performance and durability.

*Nanomaterial Production and Characterisation: Synthesizing new nanomaterials and characterizing their properties for various industrial and technological applications.

*Carbon Dioxide Reduction: Developing innovative materials and methods for efficient CO2 capture and conversion, contributing to the reduction of greenhouse gas emissions.

*Hydrogen Storage Materials: Creating safe and efficient materials for hydrogen storage, a critical component in the shift towards clean energy.

*Suzuki Coupling Electrocatalysis: Enhancing the efficiency of Suzuki coupling reactions through novel electrocatalysts, impacting pharmaceuticals and fine chemicals manufacturing.

*Solid State Electrolytes: Designing high-performance solid electrolytes for safer and more efficient batteries.

*Li and Na-ion Battery Electrodes: Developing advanced electrode materials for lithium and sodium-ion batteries to improve energy density and battery life.

Techniques and Technologies

Our lab is equipped with state-of-the-art facilities to push the boundaries of material science. We have the facilites to manufacture and synthesise materials in air-free environemnts, which is important for many energy technologies including various types of batteries.

In terms of battery testing we have an 80 channel battery cycler and a 32 channel battery cycler that can do more advanced analysis including EIS (Electrochemical Impedance Spectroscopy).

Our group are also regular users of the synchotron at Diamond light source and of neutron scattering at ISIS neutron and muon source, both of which are in Oxfordshire.

Publications

solid heart iconPublications of specific relevance to the Centre for Sustainable Engineering

2024

bullet iconInvestigating the effect of Fe–N 5 configuration in the oxygen reduction reaction using N-heterocycle functionalized carbon nanotubes
Li Q, Zhao Q, Pedersen A, Zhang M, Lin Z, Xu Y, Cullen PL, Sapelkin A, Di Tommaso D, Titirici M-M and Jones CR
Journal of Materials Chemistry A, Royal Society of Chemistry (Rsc) vol. 12 (41), 28074-28084.  
26-09-2024
bullet iconControlling nanocluster growth through nanoconfinement: the effect of the number and nature of metal–organic framework functionalities
King J, Lin Z, Zanca F, Luo H, Zhang L, Cullen P, Danaie M, Hirscher M, Meloni S, Elena AM and Szilágyi PÁ
Physical Chemistry Chemical Physics, Royal Society of Chemistry 
01-01-2024

2023

bullet icon2023 roadmap for potassium-ion batteries
Xu Y, Titirici M, Chen J, Cora F, Cullen PL, Edge JS, Fan K, Fan L, Feng J, Hosaka T, Hu J, Huang W, Hyde TI, Imtiaz S, Kang F, Kennedy T, Kim EJ, Komaba S, Lander L, Le Pham PN, et al.
Jphys Energy, Iop Publishing vol. 5 (2) 
06-04-2023
Relevant PublicationEx Situ Characterization of 1T/2H MoS2 and Their Carbon Composites for Energy Applications, a Review
Marinov AD, Bravo Priegue L, Shah AR, Miller TS, Howard CA, Hinds G, Shearing PR, Cullen PL and Brett DJL
Acs Nano, American Chemical Society vol. 17 (6), 5163-5186.  
16-03-2023

2022

bullet iconA new high: Cannabis as a budding source of carbon-based materials for electrochemical power sources
Rana ZI, Shah AR, Llewellyn AV, Mazloomian K, McAlernon P, Miller TS, Cullen PL, Shearing PR and Brett DJL
Current Opinion in Electrochemistry, Elsevier vol. 31 
01-02-2022

2021

Relevant PublicationNeutron studies of Na-ion battery materials
Shah AR, Shutt RRC, Smith K, Hack J, Neville TP, Headen TF, Brett DJL, Howard CA, Miller TS and Cullen PL
Jphys Materials vol. 4 (4) 
27-09-2021
bullet iconA novel fuel cell design for operando energy-dispersive x-ray absorption measurements
Leach AS, Hack J, Amboage M, Diaz-Moreno S, Huang H, Cullen PL, Wilding M, Magliocca E, Miller TS, Howard CA, Brett DJL, Shearing PR, McMillan PF, Russell AE and Jervis R
Journal of Physics Condensed Matter, Iop Publishing vol. 33 (31) 
16-06-2021

2020

bullet iconRealising the electrochemical stability of graphene: scalable synthesis of an ultra-durable platinum catalyst for the oxygen reduction reaction.
Angel GMA, Mansor N, Jervis R, Rana Z, Gibbs C, Seel A, Kilpatrick AFR, Shearing PR, Howard CA, Brett DJL and Cullen PL
Nanoscale 
29-06-2020
bullet iconUse of X-ray computed tomography for understanding localised, along-the-channel degradation of polymer electrolyte fuel cells
Hack J, Rasha L, Cullen PL, Bailey JJ, Neville TP, Shearing PR, Brandon NP and Brett DJL
Electrochimica Acta vol. 352 
23-05-2020

2019

Relevant PublicationLignin-derived electrospun freestanding carbons as alternative electrodes for redox flow batteries
Jorge Sobrido A, Jervis R, Crespo Ribadeneyra M, Grogan L, Au H, Schlee P, Herou S, Neville T, Cullen P, Kok M, Hosseinaei O, Tomani P, Titirici M, Brett D and Shearing P
Carbon, Elsevier 
06-11-2019
bullet iconThe liquid structure of the solvents dimethylformamide (DMF) and dimethylacetamide (DMA)
Basma N, Cullen PL, Clancy AJ, Shaffer MSP, Skipper NT, Headen TF and Howard CA
Molecular Physics, Informa Uk Limited vol. 117 (22), 3353-3363.  
16-08-2019
bullet iconSolvation of Na– in the Sodide Solution, LiNa·10MeNH2
Seel AG, Holzmann N, Imberti S, Bernasconi L, Edwards PP, Cullen PL, Howard CA and Skipper NT
The Journal of Physical Chemistry B, American Chemical Society (Acs) vol. 123 (25), 5337-5342.  
30-05-2019
Relevant PublicationProduction of phosphorene nanoribbons
Watts MC, Picco L, Russell-Pavier FS, Cullen PL, Miller TS, Bartuś SP, Payton OD, Skipper NT, Tileli V and Howard CA
Nature, Nature Research vol. 568 (7751), 216-220.  
11-04-2019

2018

bullet iconThe structures of liquid pyridine and naphthalene: The effects of heteroatoms and core size on aromatic interactions
Headen TF, Cullen PL, Patel R, Taylor A and Skipper NT
Physical Chemistry Chemical Physics vol. 20 (4), 2704-2715.  
01-01-2018

2017

bullet iconSingle Crystal, Luminescent Carbon Nitride Nanosheets Formed by Spontaneous Dissolution
Miller TS, Suter TM, Telford AM, Picco L, Payton OD, Russell-Pavier F, Cullen PL, Sella A, Shaffer MSP, Nelson J, Tileli V, McMillan PF and Howard CA
Nano Letters vol. 17 (10), 5891-5896.  
11-10-2017
bullet iconTrajectory of the selective dissolution of charged single-walled carbon nanotubes
Buckley DJ, Hodge SA, Marco MD, Hu S, Anthony DB, Cullen PL, Mckeigue K, Skipper NT, Shaffer MSP and Howard CA
Journal of Physical Chemistry C vol. 121 (39), 21703-21712.  
05-10-2017
bullet iconInvestigation of Hot Pressed Polymer Electrolyte Fuel Cell Assemblies via X-ray Computed Tomography
Meyer Q, Mansor N, Iacoviello F, Cullen PL, Jervis R, Finegan D, Tan C, Bailey J, Shearing PR and Brett DJL
Electrochimica Acta, Elsevier Bv vol. 242, 125-136.  
01-07-2017
Relevant PublicationIonic solutions of two-dimensional materials
Cullen PL, Cox KM, Bin Subhan MK, Picco L, Payton OD, Buckley DJ, Miller TS, Hodge SA, Skipper NT, Tileli V and Howard CA
Nature Chemistry vol. 9 (3), 244-249.  
01-03-2017

2014

bullet iconProbing the charging mechanisms of carbon nanomaterial polyelectrolytes
Hodge SA, Tay HH, Anthony DB, Menzel R, Buckley DJ, Cullen PL, Skipper NT, Howard CA and Shaffer MSP
Faraday Discussions, Royal Society of Chemistry (Rsc) vol. 172, 311-325.  
01-01-2014

2013

bullet iconMultielement NMR Studies of the Liquid–Liquid Phase Separation and the Metal-to-Nonmetal Transition in Fluid Lithium– and Sodium–Ammonia Solutions
Lodge MTJH, Cullen P, Rees NH, Spencer N, Maeda K, Harmer JR, Jones MO and Edwards PP
The Journal of Physical Chemistry B, American Chemical Society (Acs) vol. 117 (42), 13322-13334.  
13-09-2013

2012

bullet iconStructure and Morphology of Charged Graphene Platelets in Solution by Small-Angle Neutron Scattering
Milner EM, Skipper NT, Howard CA, Shaffer MSP, Buckley DJ, Rahnejat KA, Cullen PL, Heenan RK, Lindner P and Schweins R
Journal of The American Chemical Society, American Chemical Society (Acs) vol. 134 (20), 8302-8305.  
14-05-2012

Grants of specific relevance to the Centre for Sustainable Engineering

solid heart iconGrants of specific relevance to the Centre for Sustainable Engineering
bullet iconICURe Programme: Sodium Soli State Battery Market Exploration
Isaac Abrahams and Patrick Cullen
£35,000 Innovate UK
07-01-2025 - 31-03-2025


bullet iconEvaluation of Hydrogen Evolution in Pressurised Reactor
Harshad Bhadeshia and Patrick Cullen
£327,520 Paramirum Limited
01-08-2022 - 05-09-2024
bullet iconAdvanced Manufacturing of 3D Porous Electrodes for Redox Flow Batteries
Ana Sobrido and Patrick Cullen
£132,524 Faraday Institution, The
01-06-2022 - 31-05-2023
bullet icon2-Dimensional Materials for Novel Battery Electrodes - Grant Transfer
Patrick Cullen
£418,627 EPSRC Engineering and Physical Sciences Research Council
05-04-2020 - 01-01-2023